Sounds like your setup is decently redundant for power and 4G with your main (non-Securifi) router.
I would recommend setting the A3S as the main then. HA devices typically talk to one controller. Wired devices (ones that do not use batteries) will typically (not always, but most do it) act as repeaters for their respective HA protocol. The A3S has build in ZigBee.
So set it as the main, position your HA devices, then carry the A3S around (it should be within about 3ft/1 mete) when adding a device. They can be further sometimes be further, depends on repeaters and all sorts of radio effects, but just move it close to be sure.
Once added that HA unit will only talk through to the main. There is a process to remove one (or all) from the Almond (or any controller) so the device can then be added to a different one. Polite to do if you want to sell something you find you do not use. Most devices also have a reset method (ZigBee mostly uses this) to clear the device, but it does not clear the controller entry. If you attempt to re-add it to the controller it will likely be added as a new device, and the previous entry will still exist and be useless (just remove it). Z-Wave is "smarter" about the remove command in that the controller removes the entry and the device resets itself at the same time.
A3S does not have a native Z-Wave radio. The frequency varies by country/region, so that was a smart call to keep the unit simpler. You can buy a pretty cheap Z-Wave USB dongle to add the capability. This also allows for changes in the technology/protocol. Z-Wave 700 was just announced. Z-Wave Plus (500) has just gotten fairly common, and there is still original Z-Wave that works fine. They are backwards compatible, but the newer features (longer range, lower power, more security in device communications) only work between devices of the newer types. Older ones will work, it will just make that segment all act as the slower/older method.
Sorry, probably more than you needed. Got going.