Thanks for the detailed response  

My iwconfig output:
wlan00    IEEE 802.11ac  ESSID:""
          Mode:Master  Frequency:5.18 GHz  Access Point: 
          Bit Rate=1.3 Gb/s   Tx-Power=19 dBm
          RTS thr:off   Fragment thr:off
          Encryption key: [3]   Security mode:open
          Power Management:off
          Link Quality=94/94  Signal level=-96 dBm  Noise level=-95 dBm
          Rx invalid nwid:2354  Rx invalid crypt:0  Rx invalid frag:0
          Tx excessive retries:0  Invalid misc:0   Missed beacon:0
wlan10    IEEE 802.11ng  ESSID:""
          Mode:Master  Frequency:2.462 GHz  Access Point: 
          Bit Rate:216.7 Mb/s   Tx-Power=20 dBm
          RTS thr:off   Fragment thr:off
          Encryption key: [3]   Security mode:open
          Power Management:off
          Link Quality=94/94  Signal level=-96 dBm  Noise level=-95 dBm
          Rx invalid nwid:2752  Rx invalid crypt:8201  Rx invalid frag:0
          Tx excessive retries:0  Invalid misc:0   Missed beacon:0
It's currently on channel 36 (there are only 4 channels available, and IIRC 80MHz will cover them all), country is UK and there are zero other 5GHz networks where I am...  Max permissable power is 200mw, which is around 23dBm IIRC.
I'll try changing it to 20MHz and see if that's any different.
J